unhybridised ‘p’ orbitals interact to form a π system which is delocalised over the whole layer. The interactions known as London dispersion forces between the layers which are separated by a distance of 3.35 A⁰are weakened by the presence of water molecules so that it is easy to cleave graphite. For this reason graphite is used as lubricant and as the ‘lead’ in pencils. • How do you understand the markings (writings) of a pencil on a paper? When we write with a pencil, the interlayer attractions breakdown and leave graphite layers on the paper. Pencil marks are easy to remove from paper with an eraser because, the layers do not bind strongly to the paper. Graphite is a good conductor of electricity because of the delocalised π electron system. Buckminsterfullerene (C60) Buckminsterfullerenes are molecules of varying sizes that are composed entirely of carbon. The arrangement of these molecules leads to the form of a hollow sphere, ellipsoid, or tube depending upon their orientations. Fullerenes are formed when vaporized carbon condenses in an atmosphere of an inert gas.
Buckyballs: Spherical fullerenes are also called buckyballs. Buckminsterfullerene (C60) contains nearly spherical C60 molecules with the shape of a soccer ball.