Amorphous forms Different amorphous allotropes of carbon are: Coal; Coke; Wood Charcoal;Animal charcoal;Lamp black;Gas carbon; Petroleum coke;Sugar charcoal. Crystalline forms Carbon atoms can arrange themselves into different hybridised chemical bonds. Therefore they exhibit different physical and chemical structures such as diamond and graphite.Carbon in solid phase can exist in three crystalline allotropic forms : diamond, graphite and buckminsterfullerene. Diamond and graphite form covalent network structures whereas buckminsterfullerene has a molecular solid structure with discrete C60 molecules.As these crystalline allotropes differ in their structures,they possess different physical properties. Diamond In diamond each carbon atom undergoes in its excited state sp3 hybridisation.Hence, each carbon atom has a tetrahedral environment.The three dimensional structure of diamond is as shown: As C-C bonds are very strong any attempt to distort the diamond structure requires large amount of energy.Hence diamond is one of the hardest materials known. Graphite Graphite forms a two dimensional layer structure with C-C bonds within the layers. There are relatively weak interactions between the layers. In the layer structure, the carbon atoms are in a trigonalplanar environment.This is consistent with each carbon atom in sp2 hybridisation. Interactions between the sp2orbitals (overlaps) lead to the formation of C-C bonds. Each carbon atom is with one unhybridised ā€˜p’ orbital. The


page no:60

Home