The possibility of bonds formation by a carbon atom is as follows:

  1. a) i. Four single covalent bonds, with atoms of same element like hydrogen, Chlorine

    Eg: CH4 , CCl4 or H | H – C – H | H , C l | Cl – C – Cl | Cl

    ii. Four single covalent bonds with atoms of different elements ;

    Eg: H | H – C – Cl | Br

    b) Carbon atoms may form one double bond and two single bonds HH

    Eg: CC HH HO ; H CC HH

    c) Carbon atom may form one single bond and a triple bond

    Eg: H–C C–H or CH3 –C N or carbon atoms may also    form two double bonds as in CH2 = C = CH2

As per valence bond theory (see chapter-8, chemical bonding), the four unpaired electrons in a carbon atom are shown by suggesting excited state to carbon atom.

Electronic configuration of carbon ( ground state):

1s2 2s2 (or) 1s2 2s2 2px 12py 12pz0


Carbon (ground state)

Electronic cknfiguration of carbon (excited state):

1s2 2s1 2px 12py 12pz1

Carbon (excited state)



page no:254

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