• Can you explain the reasons for all these?
Ionic bond is formed between atoms of elements with electronegativity
difference equal to or greater than 1.9.
In ionic bond formation, you have noticed that atoms either lose
electrons or gain electrons to attain octet in valence shell. i.e., in an ionic
bond, transfer of electrons takes place between combining atoms.
The tendency of losing electrons to form cations (or) gaining electron
to form anions depends on the following factors:
i. Atomic size
ii. Ionisation potential
iii. Electron affinity
iv. Electronegativity
The atoms of elements with low ionisation energy, low electron affinity
high atomic size and low electronegativity form cations.
The atoms of elements with high ionisation potential, high electron
affinity, small atomic size and high electronegativity from anions
G.N. Lewis (1916) proposed that atoms of some elements could
achieve an octet in their valence shells without transfer of electrons
between them. They can attain octet configuration in their valence shells
by sharing the valence electrons with one or more atoms.
The electrons shared between two atoms belong to both the atoms and
the sharing of electrons between them leads to the formation of a chemical
bond known as covalent bond.
For example, take two fluorine atoms which form a stable molecule.
Each fluorine atom contributes one electron for bonding and the electron
pair that is formed in this way is mutually shared by both the fluorine
atoms. Each atom in the F2
molecule has an octet of valence electrons.